Slope destabilization provoked by dissociation of gas hydrates in the Outer Carpathian basin during the Oligocene : sedimentological, petrographic, isotopic and biostratigraphic record

Sedimentological, biostratigraphic, petrographic, and stable C and O isotope study was carried out on chaotic complexes hosting carbonate concretions in the uppermost Oligocene successions of the Outer Carpathians. These chaotic complexes reveal a range of sedimentary features indicative of intrabasinal, submarine mass-wasting deposition, including soft-sediment deformation, brecciation, homogenization and fluidization of the parent material. Apart from carbonate concretions, they enclose blocks of rocks having lithologies typical for the underlying Oligocene strata. The concretions exhibit extremely depleted δ13C (by down to −51.3‰) indicating anaerobic oxidation of methane, whereas their δ18O values are strongly enriched relative to coeval brackish basin water indicating dissociation of gas hydrates as the main fluid source. These data and the geotectonic context imply that the chaotic complexes formed as submarine slumps on a N-inclined paleoslope of the basin in consequence to tectonically-induced dissociation of gas hydrates. Hydrates were destabilized within the sediments due to synorogenic uplift, related to northward progradation of the accretionary prism. These slumps and hosted concretions were dated by the combination of calcareous nannoplankton and organic-walled dinoflagellate cysts. The age of concretions indicated by dinoflagellate cyst assemblages always overlaps with that of the surrounding slump matrix determined by both micropaleontological groups. Together with sedimentological and petrographic evidence, this confirms that the concretions formed in situ within the sediment shortly after deposition and prior to slumping. Hydrate dissociation, seepage of methane-charged fluids and the resultant slope destabilization was not an isolated event, but a continuous process occurring diachronously in front of N-prograding accretionary prism during Oligocene, at least from early NP23 to late NP25 biozones. The stable C and O isotope analysis of carbonate concretions was crucial for this research, because the low δ13C and high δ18O values were the only preserved indicators of anaerobic oxidation of methane and dissociation of gas hydrates in the basin, respectively. Because, the concretions are composed of a mixture of dolomite and calcite, a semiautomatic method for measuring C and O isotope composition selectively for calcite and dolomite (Baudrand et al., 2012) was applied, which provided conclusive results. These measurements were combined with detailed petrographic investigations, which enabled assessment of isotopic composition for various carbonate constituents separately, e.g. sedimentary calcite (biogenic and detrital), early and late calcite cements, dolomite cement. They showed that the concretionary microcrystalline calcite was the main cement that precipitated due to hydrate dissociation and subsequent methane oxidation. This approach can provide valuable information when applied to other authigenic carbonates composed of a mixture of dolomite and calcite.