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Cross-metathesis of technical grade methyl oleate for the synthesis of bio-based polyesters and polyamides

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dc.abstract.enFatty acid methyl esters (FAMEs), despite being currently used mainly as a biodiesel, could be also a source of various building blocks. Their cross-metathesis allows the production of diesters—attractive bio-based monomers. However, most of the existing reports from academic research groups are mainly restricted to pure methyl oleate. With the goal of future industrial feasibility, a process for the self-cross metathesis of technical grade methyl oleate, which means containing a significant amount (20 wt%) of methyl linoleate, has been developed. The resulting dimethyl octadec-9-enedioate has been obtained with high selectivity and in good yield. Subsequent polycondensation with a co-monomer (diol or diamine) resulted in the formation of polymeric materials which were characterized using thermogravimetric analysis and differential scanning calorimetry.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorOrtiz, Pablo
dc.contributor.authorSantos, Sergio
dc.contributor.authorGrela, Karol
dc.contributor.authorCésar, Vincent
dc.contributor.authorKrzesiński, Paweł
dc.date.accessioned2024-01-24T20:55:23Z
dc.date.available2024-01-24T20:55:23Z
dc.date.copyright2023-09-28
dc.date.issued2023
dc.description.accesstimeAT_PUBLICATION
dc.description.financeNie dotyczy
dc.description.number8
dc.description.versionFINAL_PUBLISHED
dc.description.volume1
dc.identifier.doi10.1039/D3SU00305A
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/103965
dc.identifier.weblinkhttp://pubs.rsc.org/en/content/articlepdf/2023/SU/D3SU00305A
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofRSC sustainability
dc.relation.pages2033-2037
dc.rightsCC-BY
dc.sciencecloudnosend
dc.titleCross-metathesis of technical grade methyl oleate for the synthesis of bio-based polyesters and polyamides
dc.typeJournalArticle
dspace.entity.typePublication