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The spin-orbit coupling of the 61Σ+ and 43Π states in KCs: Observation and deperturbation

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dc.abstract.enEnergies of 1655 rovibrational levels of the mutually perturbed and states in KCs were measured in a series of experiments employing polarization labelling spectroscopy technique. The experimental term values of the complex in KCs were used in coupled-channels deperturbation analysis which took explicitly into account the spin-orbit coupling of the and states. The empirical deperturbation treatment was supported by ab initio electronic structure calculation of adiabatic potentials of the interacting states and of the corresponding spin-orbit coupling matrix element as a function of internuclear distance.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorPashov, A.
dc.contributor.authorPazyuk, E.A.
dc.contributor.authorStolyarov, A.V.
dc.contributor.authorKowalczyk, Paweł
dc.contributor.authorSzczepkowski, Jacek
dc.contributor.authorGrochola, Anna
dc.contributor.authorJastrzębski, Włodzimierz
dc.date.accessioned2024-01-26T10:48:00Z
dc.date.available2024-01-26T10:48:00Z
dc.date.issued2019
dc.description.financeNie dotyczy
dc.description.volume239
dc.identifier.doi10.1016/J.JQSRT.2019.106650
dc.identifier.issn0022-4073
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/123164
dc.identifier.weblinkhttps://api.elsevier.com/content/article/PII:S0022407319305515?httpAccept=text/xml
dc.languageeng
dc.pbn.affiliationphysical sciences
dc.relation.ispartofJournal of Quantitative Spectroscopy and Radiative Transfer
dc.relation.pages106650
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titleThe spin-orbit coupling of the 61Σ+ and 43Π states in KCs: Observation and deperturbation
dc.typeJournalArticle
dspace.entity.typePublication