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The spin-orbit coupling of the 61Σ+ and 43Π states in KCs: Observation and deperturbation
dc.abstract.en | Energies of 1655 rovibrational levels of the mutually perturbed and states in KCs were measured in a series of experiments employing polarization labelling spectroscopy technique. The experimental term values of the complex in KCs were used in coupled-channels deperturbation analysis which took explicitly into account the spin-orbit coupling of the and states. The empirical deperturbation treatment was supported by ab initio electronic structure calculation of adiabatic potentials of the interacting states and of the corresponding spin-orbit coupling matrix element as a function of internuclear distance. |
dc.affiliation | Uniwersytet Warszawski |
dc.contributor.author | Pashov, A. |
dc.contributor.author | Pazyuk, E.A. |
dc.contributor.author | Stolyarov, A.V. |
dc.contributor.author | Kowalczyk, Paweł |
dc.contributor.author | Szczepkowski, Jacek |
dc.contributor.author | Grochola, Anna |
dc.contributor.author | Jastrzębski, Włodzimierz |
dc.date.accessioned | 2024-01-26T10:48:00Z |
dc.date.available | 2024-01-26T10:48:00Z |
dc.date.issued | 2019 |
dc.description.finance | Nie dotyczy |
dc.description.volume | 239 |
dc.identifier.doi | 10.1016/J.JQSRT.2019.106650 |
dc.identifier.issn | 0022-4073 |
dc.identifier.uri | https://repozytorium.uw.edu.pl//handle/item/123164 |
dc.identifier.weblink | https://api.elsevier.com/content/article/PII:S0022407319305515?httpAccept=text/xml |
dc.language | eng |
dc.pbn.affiliation | physical sciences |
dc.relation.ispartof | Journal of Quantitative Spectroscopy and Radiative Transfer |
dc.relation.pages | 106650 |
dc.rights | ClosedAccess |
dc.sciencecloud | nosend |
dc.title | The spin-orbit coupling of the 61Σ+ and 43Π states in KCs: Observation and deperturbation |
dc.type | JournalArticle |
dspace.entity.type | Publication |