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Functionalization of Graphene by π–π Stacking with C60/C70/Sc3N@C80 Fullerene Derivatives for Supercapacitor Electrode Materials

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dc.abstract.enNon-covalent modification of graphene is one of the strategies used for enhancing its energy storage properties. Herein, we report the design and synthesis of a series of fullerene derivatives that are capable of assembly on graphene sheets by π–π stacking interactions. Newly synthesized graphene-fullerene hybrid nanomaterials were characterized using spectroscopic and microscopic techniques. In order to determine the specific capacitance of obtained electrode materials galvanostatic charge-discharge measurements were performed. The obtained results allowed the determination of which fullerene core and type of substituent introduced on its surface can increase the capacitance of resulting electrode. Benefiting from introduced fullerene derivative molecules, graphene with naphthalene functionalized C70 fullerene showed specific capacitance enhanced by as much as 15% compared to the starting material.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorKrogul-Sobczak, Agnieszka
dc.contributor.authorPiotrowski, Piotr
dc.contributor.authorGrebowski, Jacek
dc.contributor.authorFedorczyk, Agata
dc.date.accessioned2024-01-25T01:40:13Z
dc.date.available2024-01-25T01:40:13Z
dc.date.copyright2022-03-11
dc.date.issued2022
dc.description.accesstimeAT_PUBLICATION
dc.description.financeŚrodki finansowe, o których mowa w art. 365 pkt. 2 ustawy
dc.description.number1
dc.description.versionFINAL_PUBLISHED
dc.description.volume8
dc.identifier.doi10.3390/C8010017
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/107612
dc.identifier.weblinkhttps://www.mdpi.com/2311-5629/8/1/17/pdf
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofC-Journal of Carbon Research
dc.relation.pages17
dc.rightsCC-BY
dc.sciencecloudnosend
dc.subject.engraphene
dc.subject.enfullerene
dc.subject.ensupercapacitor
dc.titleFunctionalization of Graphene by π–π Stacking with C60/C70/Sc3N@C80 Fullerene Derivatives for Supercapacitor Electrode Materials
dc.typeJournalArticle
dspace.entity.typePublication