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Vitamin B12 and a metal-organic framework enable the photocatalytic generation of alkyl radicals

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cris.lastimport.scopus2024-02-12T20:15:02Z
dc.abstract.enA versatile Co-catalyst - vitamin B12 (cobalamin) - can be photochemically reduced to its catalytically active Co(I) form under visible light irradiation, in the presence of MIL-125-NH2(Ti) as a photocatalyst and utilized for the generation of alkyl radicals. The prior reduction of cobalamin to the Co(II) form is not required in this method.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorGryko, Dorota
dc.contributor.authorChmielewski, Michał
dc.contributor.authorChołuj, Artur
dc.contributor.authorDworakowski, Krzysztof
dc.date.accessioned2024-01-26T11:49:39Z
dc.date.available2024-01-26T11:49:39Z
dc.date.copyright2023-08-22
dc.date.issued2023
dc.description.accesstimeAT_PUBLICATION
dc.description.financeNie dotyczy
dc.description.versionFINAL_PUBLISHED
dc.identifier.doi10.1039/D3CC02941G
dc.identifier.issn1359-7345
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/124684
dc.identifier.weblinkhttp://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC02941G
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofChemical Communications
dc.rightsCC-BY-NC
dc.sciencecloudnosend
dc.titleVitamin B12 and a metal-organic framework enable the photocatalytic generation of alkyl radicals
dc.typeJournalArticle
dspace.entity.typePublication