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Axially Chirac Racemic Half-Sandwich Nickel(II) Complexes by Ring-Closing Metathesis

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cris.lastimport.scopus2024-02-12T20:26:08Z
dc.abstract.enA remarkable nickelacycle has been synthesised via olefin metathesis of the α,ω-diene complex [Ni(η5-C5H4R)(Br)(NHC)] (R = C(CH3)2CH2CH[double bond, length as m-dash]CH2, NHC = 1-(6-hexenyl)-3-(2,4,6-trimethylphenyl)-imidazol-2-ylidene). Single-crystal X-ray analysis reveals a helical shape of the molecule and stretching of some interatomic distances in the Ni(II) coordination sphere. The Cp-NHC tethered complex shows catalytic activity resembling that of the parent complexes.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorBanach, Lukasz
dc.contributor.authorBuchalski, Piotr
dc.contributor.authorKamiński, Radosław
dc.contributor.authorBuchowicz, Włodzimierz
dc.date.accessioned2024-01-24T16:59:43Z
dc.date.available2024-01-24T16:59:43Z
dc.date.copyright2017-02-13
dc.date.issued2017
dc.description.accesstimeAT_PUBLICATION
dc.description.financeNie dotyczy
dc.description.number12
dc.description.versionFINAL_PUBLISHED
dc.description.volume46
dc.identifier.doi10.1039/C6DT04811K
dc.identifier.issn1477-9226
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/101389
dc.identifier.weblinkhttp://pubs.rsc.org/en/content/articlelanding/2017/dt/c6dt04811k#!divAbstract
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofDalton Transactions
dc.relation.pages3805-3808
dc.rightsCC-BY-NC
dc.sciencecloudnosend
dc.titleAxially Chirac Racemic Half-Sandwich Nickel(II) Complexes by Ring-Closing Metathesis
dc.typeJournalArticle
dspace.entity.typePublication