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Site-Selective Au+ Electroreduction in Titania Nanotubes for Electrochemical and Plasmonic Applications
cris.lastimport.scopus | 2024-02-12T20:15:24Z |
dc.abstract.en | The present study demonstrates the electrochemical and plasmonic features of gold structures grown in anodic TiO2 nanotubes by means of the electroreduction of Au+ species from a potassium dicyanoaurate electrolyte. The primary location of the electroreduced gold is in the gap between nanotubes, resulting in the formation of a gold/titania interface at the outer shell of the nanotubes. This unique configuration makes it possible to develop a specific shape of gold nanopore array, which is studied as a core− shell structure and standalone gold electrode after the selective dissolution of the titania matrix. Surface plasmon resonance, evaluated by finite-difference time-domain modeling, leads to strong electromagnetic fields and the consequent enhancement in light absorption and light scattering depending on the size, geometry, and composition of the nanostructure. The TiO 2 nanotube core promotes light localization in air and water due to its large refractive index. Numerical analysis indicates light E-field enhancement localized on the rims of titania nanotubes of the magnitude intensity of E2 > 100. |
dc.affiliation | Uniwersytet Warszawski |
dc.contributor.author | Kowalski, Damian |
dc.contributor.author | Henkiel, Patrycja |
dc.contributor.author | Juodkazis, Saulius |
dc.contributor.author | Kowalska, Ewa |
dc.date.accessioned | 2024-01-26T07:39:23Z |
dc.date.available | 2024-01-26T07:39:23Z |
dc.date.issued | 2022 |
dc.description.finance | Publikacja bezkosztowa |
dc.description.number | 6 |
dc.description.volume | 5 |
dc.identifier.doi | 10.1021/ACSANM.2C00044 |
dc.identifier.uri | https://repozytorium.uw.edu.pl//handle/item/119899 |
dc.identifier.weblink | https://pubs.acs.org/doi/pdf/10.1021/acsanm.2c00044 |
dc.language | eng |
dc.pbn.affiliation | chemical sciences |
dc.relation.ispartof | ACS Applied Nano Materials |
dc.relation.pages | 7696–7703 |
dc.rights | ClosedAccess |
dc.sciencecloud | nosend |
dc.subject.en | plasmon resonance |
dc.subject.en | TiO2 nanotubes |
dc.subject.en | anodizing |
dc.subject.en | gold nanopores |
dc.subject.en | FDTD |
dc.title | Site-Selective Au+ Electroreduction in Titania Nanotubes for Electrochemical and Plasmonic Applications |
dc.type | JournalArticle |
dspace.entity.type | Publication |