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Site-Selective Au+ Electroreduction in Titania Nanotubes for Electrochemical and Plasmonic Applications

cris.lastimport.scopus2024-02-12T20:15:24Z
dc.abstract.enThe present study demonstrates the electrochemical and plasmonic features of gold structures grown in anodic TiO2 nanotubes by means of the electroreduction of Au+ species from a potassium dicyanoaurate electrolyte. The primary location of the electroreduced gold is in the gap between nanotubes, resulting in the formation of a gold/titania interface at the outer shell of the nanotubes. This unique configuration makes it possible to develop a specific shape of gold nanopore array, which is studied as a core− shell structure and standalone gold electrode after the selective dissolution of the titania matrix. Surface plasmon resonance, evaluated by finite-difference time-domain modeling, leads to strong electromagnetic fields and the consequent enhancement in light absorption and light scattering depending on the size, geometry, and composition of the nanostructure. The TiO 2 nanotube core promotes light localization in air and water due to its large refractive index. Numerical analysis indicates light E-field enhancement localized on the rims of titania nanotubes of the magnitude intensity of E2 > 100.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorKowalski, Damian
dc.contributor.authorHenkiel, Patrycja
dc.contributor.authorJuodkazis, Saulius
dc.contributor.authorKowalska, Ewa
dc.date.accessioned2024-01-26T07:39:23Z
dc.date.available2024-01-26T07:39:23Z
dc.date.issued2022
dc.description.financePublikacja bezkosztowa
dc.description.number6
dc.description.volume5
dc.identifier.doi10.1021/ACSANM.2C00044
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/119899
dc.identifier.weblinkhttps://pubs.acs.org/doi/pdf/10.1021/acsanm.2c00044
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofACS Applied Nano Materials
dc.relation.pages7696–7703
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enplasmon resonance
dc.subject.enTiO2 nanotubes
dc.subject.enanodizing
dc.subject.engold nanopores
dc.subject.enFDTD
dc.titleSite-Selective Au+ Electroreduction in Titania Nanotubes for Electrochemical and Plasmonic Applications
dc.typeJournalArticle
dspace.entity.typePublication