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Modification of surfaces of silver nanoparticles for controlled deposition of silicon, manganese, and titanium dioxides

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cris.lastimport.scopus2024-02-12T20:17:55Z
dc.abstract.enIn this work we show that nanometric-thick layers of SiO2, MnO2, and TiO2 may be effectively deposited on various silver nanoparticles (including cubic Ag nanoparticles) covered by a very thin (below 0.4 nm) layer of silver sulphide. The background in Raman measurements generated by sulphide-protected Ag nanoparticles is significantly smaller than that for analogous Ag nanoparticles protected by a monolayer formed from alkanethiols – depositing alkanethiols on a surface of anisotropic silver nanoparticles is the current standard method used for protecting a surface of Ag nanoparticles before depositing a layer of silica. Because of significantly smaller generated Raman background, Ag@SiO2 nanostructures with an Ag2S linkage layer between the silver core and the silica shell are very promising low-background electromagnetic nanoresonators for carrying out Raman analysis of various surfaces – especially using what is known as shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS). Sample SHINERS analyses of various surfaces (including pesticide-contaminated surfaces of tomatoes) using cubic-Ag@SiO2 nanoparticles as electromagnetic nanoresonators are also presented.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorKudelski, Andrzej
dc.contributor.authorAbdulrahman, Heman
dc.contributor.authorKrajczewski, Jan
dc.date.accessioned2024-01-25T12:52:43Z
dc.date.available2024-01-25T12:52:43Z
dc.date.issued2018
dc.description.financeNie dotyczy
dc.description.volume427
dc.identifier.doi10.1016/J.APSUSC.2017.08.163
dc.identifier.issn0169-4332
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/112820
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofApplied Surface Science
dc.relation.pages334 - 339
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enShell-isolated nanoparticle-enhanced
dc.subject.enRaman spectroscopy
dc.subject.enSHINERS
dc.subject.enSurface-enhanced raman spectroscopy
dc.subject.enSERS
dc.subject.enAg@SiO2
dc.subject.enCubic Ag nanoparticles
dc.titleModification of surfaces of silver nanoparticles for controlled deposition of silicon, manganese, and titanium dioxides
dc.typeJournalArticle
dspace.entity.typePublication