Artykuł w czasopiśmie
Brak miniatury
Licencja
ClosedAccessDostęp zamknięty
 

Specialized Ruthenium Olefin Metathesis Catalysts Bearing Bulky Unsymmetrical NHC Ligands: Computations, Synthesis, and Application

Uproszczony widok
cris.lastimport.scopus2024-02-12T20:18:41Z
dc.abstract.enSecond-generation ruthenium olefin metathesis catalysts were investigated with systematic variation of the unsymmetrical uNHC ligands. Depending on the uNHC steric bulk, the catalysts exhibited different activity and selectivity in metathesis reactions. DFT calculations and X-ray crystallographic data were used to understand the influence of uNHC ligand structure on the catalyst properties. Furthermore, the catalysts were examined in the context of reactions that are problematic for general-purpose Ru catalysts, including industrially important self-cross metathesis of α-olefins and ethenolysis of ethyl oleate.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorGajda, Roman
dc.contributor.authorMałecki, Paweł
dc.contributor.authorGajda, Katarzyna
dc.contributor.authorWoźniak, Krzysztof
dc.contributor.authorTrzaskowski, Bartosz
dc.contributor.authorKajetanowicz, Anna
dc.contributor.authorGrela, Karol
dc.date.accessioned2024-01-26T07:54:28Z
dc.date.available2024-01-26T07:54:28Z
dc.date.issued2019
dc.description.financeNie dotyczy
dc.description.number1
dc.description.volume9
dc.identifier.doi10.1021/ACSCATAL.8B04783
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/120311
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofACS Catalysis
dc.relation.pages587-598
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enolefin metathesis
dc.subject.enruthenium
dc.subject.enligands
dc.subject.enN-heterocyclic carbenes
dc.subject.encatalysis
dc.subject.enselectivity
dc.subject.enethenolysis
dc.titleSpecialized Ruthenium Olefin Metathesis Catalysts Bearing Bulky Unsymmetrical NHC Ligands: Computations, Synthesis, and Application
dc.typeJournalArticle
dspace.entity.typePublication