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Design of a D3h-symmetry prismatic tris-(ferrocene-1,1′-diyl) molecular cage bearing boronate ester linkages

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cris.lastimport.scopus2024-02-12T20:06:22Z
dc.abstract.enThis paper presents a simple, highly selective, and efficient (isolated yield of 68%) synthesis of a novel D3h-symmetry prismatic tris-(ferrocene-1,1′-diyl) organic cage (FcB-cage) by incorporating a boronate ester as a linkage motif. 1,1′-Diboronated derivatives of ferrocene and 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) were used as the starting materials. The synthesized cage was comprehensively characterized by spectroscopic and microscopic methods, powder X-ray diffraction, thermogravimetry and voltammetry. Cyclic voltammetry analysis revealed the electronic communication between the ferrocene units of the FcB-cage. In addition, to better understand the mechanism behind the synthesis of such a cage, as well as its geometric properties, we performed DFT calculations.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorKasprzak, Artur
dc.contributor.authorLuliński, Sergiusz
dc.contributor.authorDurka, Krzysztof
dc.contributor.authorKazimierczuk, Krzysztof
dc.contributor.authorNowicka, Anna
dc.contributor.authorKrzyżanowski, Maurycy
dc.date.accessioned2024-01-24T21:35:38Z
dc.date.available2024-01-24T21:35:38Z
dc.date.copyright2022-06-22
dc.date.issued2022
dc.description.accesstimeAT_PUBLICATION
dc.description.financePublikacja bezkosztowa
dc.description.number27
dc.description.versionFINAL_PUBLISHED
dc.description.volume51
dc.identifier.doi10.1039/D2DT01306A
dc.identifier.issn1477-9226
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/104604
dc.identifier.weblinkhttp://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01306A
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofDalton Transactions
dc.relation.pages10601-10611
dc.rightsCC-BY-NC
dc.sciencecloudnosend
dc.titleDesign of a D3h-symmetry prismatic tris-(ferrocene-1,1′-diyl) molecular cage bearing boronate ester linkages
dc.typeJournalArticle
dspace.entity.typePublication