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Britholite group minerals from REE‐Rich lithologies of Keivy alkali granite — nepheline syenite complex, Kola Peninsula, NW Russia

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dc.abstract.enThe Keivy alkali granite‐nepheline syenite complex, Kola Peninsula, NW Russia, contains numerous associated Zr‐REE‐Y‐Nb occurrences and deposits, formed by a complex sequence of magmatic, late‐magmatic, and post‐magmatic (including pegmatitic, hydrothermal, and metasomatic) processes. The REE‐rich lithologies have abundant (some of economic importance) and diverse britholite group minerals. The REE and actinides distribution in host rocks indicates that the emanating fluids were alkaline, with significant amounts of F and CO2. From chemical studies (REE and F variations) of the britholites the possible fluid compositions in different lithologies are proposed. Fluorbritholite‐(Y) and britholite‐(Y) from products of alkali granite (mineralized granite, pegmatite, quartzolite) formed under relatively high F activity in fluids with low CO2/H2O ratio. The highest F and moderate CO2 contents are characteristic of fluid from a mineralized nepheline syenite, resulting in crystallization of fluorbritholite‐(Ce). Britholite group minerals (mainly fluorcalciobritholite and ‘calciobritholite’) from a nepheline syenite pegmatite formed from a fluid with composition changing from low F and high CO2 to moderate F and CO2. An extremely high F content is revealed for metasomatizing fluids emanating from alkali granitic magma and which affected the basic country rocks. The dominant substitution scheme for Keivy britholites is REE3+ + Si4+ = Ca2+ + P5+, showing the full range of ‘britholite’ and ‘calciobritholite’ compositions up to theoretical apatite.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorZozulya, Dmitry
dc.contributor.authorLyalina, Lyudmila
dc.contributor.authorMacdonald, Ray
dc.contributor.authorBagiński, Bogusław
dc.contributor.authorSavchenko, Yevgeny
dc.contributor.authorJokubauskas, Petras
dc.date.accessioned2024-01-24T18:55:21Z
dc.date.available2024-01-24T18:55:21Z
dc.date.copyright2019-11-27
dc.date.issued2019
dc.description.accesstimeAT_PUBLICATION
dc.description.financeNie dotyczy
dc.description.number9
dc.description.versionFINAL_PUBLISHED
dc.description.volume732
dc.identifier.doi10.3390/MIN9120732
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/102548
dc.identifier.weblinkhttps://doi.org/10.3390/min9120732
dc.languageeng
dc.pbn.affiliationearth and related environmental sciences
dc.relation.ispartofMinerals
dc.relation.pages732
dc.rightsCC-BY
dc.sciencecloudnosend
dc.subject.enbritholite group minerals
dc.subject.enalkali granite
dc.subject.ennepheline syenite
dc.subject.enpegmatite
dc.subject.enquartzolite
dc.subject.enmetasomatite
dc.subject.enfluid composition
dc.subject.enKeivy
dc.subject.enKola Peninsula
dc.subject.enRussia
dc.titleBritholite group minerals from REE‐Rich lithologies of Keivy alkali granite — nepheline syenite complex, Kola Peninsula, NW Russia
dc.typeJournalArticle
dspace.entity.typePublication