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Predicted Mutual Solubilities in Water + C5-C12 Hydrocarbon Systems. Results at 298 K

cris.lastimport.scopus2024-02-12T20:12:25Z
dc.abstract.enMutual solubilities of water with n-alkanes, cycloalkanes, iso-alkanes (branched alkanes), kenes, alkynes, alkadienes, and alkylbenzenes were calculated at 298 K for 153 systems not yet measured. Recommended data for 64 systems reported in the literature were compared with the predicted values. The solubility of the hydrocarbons in water was calculated with a thermodynamically based equation, which depends on specific properties of the hydrocarbon. The concentration in the second coexisting liquid phase (water in hydrocarbon) was calculated using liquid-liquid equilibrium with an equation of state, which takes into account the self-association of water and co-association of water with π-bonds of the hydrocarbons.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorOracz, Paweł
dc.contributor.authorGóral, Marian
dc.date.accessioned2024-01-25T17:32:21Z
dc.date.available2024-01-25T17:32:21Z
dc.date.copyright2021-12-16
dc.date.issued2021
dc.description.accesstimeAT_PUBLICATION
dc.description.financeŚrodki finansowe, o których mowa w art. 365 pkt. 2 ustawy
dc.description.number4
dc.description.versionFINAL_PUBLISHED
dc.description.volume5
dc.identifier.doi10.3390/CHEMENGINEERING5040089
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/116891
dc.identifier.weblinkhttps://doi.org/10.3390/chemengineering5040089
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofChemEngineering
dc.relation.pages89
dc.rightsCC-BY
dc.sciencecloudnosend
dc.subject.enbinary systems
dc.subject.enliquid–liquid equilibria
dc.subject.enreference data
dc.subject.enhydrocarbon
dc.subject.enwater
dc.subject.enaqueous solubility of hydrocarbon
dc.titlePredicted Mutual Solubilities in Water + C5-C12 Hydrocarbon Systems. Results at 298 K
dc.typeJournalArticle
dspace.entity.typePublication