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Paramagnetic Liquid Crystals With Close π–π Packing: The Effect of Blatter Radical Planarization on Behavior of Bent‐Core Mesogens

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dc.abstract.enA new, 19 π-delocalized electrons planar Blatter radical building block was developed and used to obtain paramagnetic bent-core liquid crystals. The mesogens were investigated by optical, thermal, powder XRD and DFT methods in the pure form and as binary mixtures. Compar- ison of their properties with those of the classical Blatter radical analogues revealed that planarization of the central angular element results in a significantly higher stability of the mesophases and increased molecular organization suit-able for the formation of ordered banana and columnar mesophases with tighter π–π interactions. These results indicate access to a new, potentially rich class of functional paramagnetic soft materials
dc.affiliationUniwersytet Warszawski
dc.contributor.authorKaszyński, Piotr
dc.contributor.authorKapuściński, Szymon
dc.contributor.authorJakubowski, Rafał
dc.contributor.authorPociecha, Damian
dc.contributor.authorCigl, Martin
dc.date.accessioned2024-01-25T16:13:10Z
dc.date.available2024-01-25T16:13:10Z
dc.date.issued2023
dc.description.financeNie dotyczy
dc.description.number15
dc.description.volume29
dc.identifier.doi10.1002/CHEM.202203288
dc.identifier.issn0947-6539
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/115491
dc.identifier.weblinkhttps://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.202203288
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofChemistry - A European Journal
dc.relation.pagese202203288
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titleParamagnetic Liquid Crystals With Close π–π Packing: The Effect of Blatter Radical Planarization on Behavior of Bent‐Core Mesogens
dc.typeJournalArticle
dspace.entity.typePublication