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Anion Metathesis in Facile Preparation of Olefin Metathesis Catalysts Bearing a Quaternary Ammonium Chloride Tag

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dc.abstract.enEasy and efficient method for preparation of all-chloro ruthenium catalysts bearing a quaternary ammonium tag was developed. The key anion metathesis reaction was made with AgCl, and the facile recycling of silver wastes was demonstrated. The developed method transforms more accessible, yet poorly characterised mixed chloro/iodo Ru complexes into valuable all-chloro catalysts, useful in aqueous metathesis. Practical utility of the developed anion metathesis reaction was demonstrated by preparation of a commercial Ru catalyst, StickyCat™, on a 5 gram scale.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorPiątkowski, Jakub
dc.contributor.authorPatrzałek, Michał
dc.contributor.authorKajetanowicz, Anna
dc.contributor.authorGrela, Karol
dc.date.accessioned2024-01-24T16:39:34Z
dc.date.available2024-01-24T16:39:34Z
dc.date.issued2019
dc.description.financeNie dotyczy
dc.description.number17
dc.description.volume30
dc.identifier.doi10.1055/S-0037-1611834
dc.identifier.issn0936-5214
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/100723
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofSynlett
dc.relation.pages1981-1987
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enion exchange
dc.subject.enmetathesis
dc.subject.enpolar solvents
dc.subject.ensilver chloride
dc.subject.entagged catalysts
dc.titleAnion Metathesis in Facile Preparation of Olefin Metathesis Catalysts Bearing a Quaternary Ammonium Chloride Tag
dc.typeJournalArticle
dspace.entity.typePublication