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Olefination with Sulfonyl Halides and Esters: Scope, Limitations, and Mechanistic Studies of the Hawkins Reaction

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cris.lastimport.scopus2024-02-12T20:23:56Z
dc.abstract.enCarbanions of alkanesulfonyl halides and esters react with nonenolizable carbonyl compounds to give olefins. Mechanistic studies reveal that initial aldol-type addition of the carbanions is followed by cyclization–fragmentation to alkenes, and the leaving group on the sulfonyl moiety (RSO2X) controls carbanion stability and rate of the olefin formation.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorGórski, Bartosz
dc.contributor.authorBarbasiewicz, Michał
dc.contributor.authorBasak, Tymoteusz
dc.contributor.authorTalko, Allicja
dc.date.accessioned2024-01-25T15:43:52Z
dc.date.available2024-01-25T15:43:52Z
dc.date.issued2017
dc.description.financeNie dotyczy
dc.description.number7
dc.description.volume19
dc.identifier.doi10.1021/ACS.ORGLETT.7B00517
dc.identifier.issn1523-7060
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/114583
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofOrganic Letters
dc.relation.pages1756–1759
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titleOlefination with Sulfonyl Halides and Esters: Scope, Limitations, and Mechanistic Studies of the Hawkins Reaction
dc.typeJournalArticle
dspace.entity.typePublication