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Direct enantiomeric discrimination through antisymmetric hyperfine coupling

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cris.lastimport.scopus2024-02-12T20:10:27Z
dc.abstract.enChiral open-shell molecules possessing permanent electric dipole moments have an EPR signal at the difference frequency of the electron and nuclear resonances, allowing direct enantiomeric discrimination by signal phase. The effect depends on the vector antisymmetry of the hyperfine coupling. Quantum chemistry suggests chiral bisfluorene methyl radical derivatives as promising for experiments.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorGarbacz, Piotr
dc.contributor.authorVaara, Juha
dc.date.accessioned2024-01-24T21:54:01Z
dc.date.available2024-01-24T21:54:01Z
dc.date.copyright2021-07-29
dc.date.issued2021
dc.description.accesstimeAT_PUBLICATION
dc.description.financeŚrodki finansowe, o których mowa w art. 365 pkt. 2 ustawy
dc.description.number67
dc.description.versionFINAL_PUBLISHED
dc.description.volume57
dc.identifier.doi10.1039/D1CC02579A
dc.identifier.issn1359-7345
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/104938
dc.identifier.weblinkhttp://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC02579A
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofChemical Communications
dc.relation.pages8264-8267
dc.rightsCC-BY-NC
dc.sciencecloudnosend
dc.titleDirect enantiomeric discrimination through antisymmetric hyperfine coupling
dc.typeJournalArticle
dspace.entity.typePublication