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Simple and Robust Immobilization of a Ruthenium Olefin Metathesis Catalyst Inside MOFs by Acid−Base Reaction

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cris.lastimport.scopus2024-02-12T19:02:38Z
dc.abstract.enThe first successful immobilization of a transition-metal catalyst inside MOFs by an acid−base reaction has been described. Simple absorption of a commercially available, amino-tagged, Hoveyda−Grubbs type ruthenium olefin metathesis catalyst inside an easy to make, Brønsted acidic MOF, (Cr)MIL-101-SO3H, yields a heterogeneous catalyst, which is stable even in very polar, “green” solvents, such as dimethyl carbonate and 2-propanol. The catalyst gives essentially ruthenium-free products upon simple filtration.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorChołuj, Artur
dc.contributor.authorKarczykowski, Robert
dc.contributor.authorChmielewski, Michał
dc.date.accessioned2024-01-26T07:37:05Z
dc.date.available2024-01-26T07:37:05Z
dc.date.issued2019
dc.description.financeNie dotyczy
dc.description.number18
dc.description.volume38
dc.identifier.doi10.1021/ACS.ORGANOMET.9B00281
dc.identifier.issn0276-7333
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/119831
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofOrganometallics
dc.relation.pages3392−3396
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titleSimple and Robust Immobilization of a Ruthenium Olefin Metathesis Catalyst Inside MOFs by Acid−Base Reaction
dc.typeJournalArticle
dspace.entity.typePublication