Artykuł w czasopiśmie
Brak miniatury
Licencja
ClosedAccessDostęp zamknięty
 

Metal-Free <i>S</i>-Arylation of Phosphorothioate Diesters and Related Compounds with Diaryliodonium Salts

Uproszczony widok
cris.lastimport.scopus2024-02-12T20:54:50Z
dc.abstract.enWe developed a direct metal-free S-arylation of phosphorothioate diesters using diaryliodonium salts. The method allows for the preparation under simple conditions of a broad range of S-aryl phosphorothioates, including complex molecules (e.g., dinucleotide or TADDOL derivatives), as well as other related organophosphorus compounds arylated at a chalcogen. The reaction proceeds with a full retention of the stereogenic center at the phosphorus atom, opening convenient access to P-chiral products. The mechanism of the reaction was established using DFT calculations.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorSarkar, Sudeep
dc.contributor.authorKałek, Marcin
dc.date.accessioned2024-01-25T11:27:45Z
dc.date.available2024-01-25T11:27:45Z
dc.date.issued2023
dc.description.financePublikacja bezkosztowa
dc.description.number4
dc.description.volume25
dc.identifier.doi10.1021/ACS.ORGLETT.2C04310
dc.identifier.issn1523-7060
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/112323
dc.identifier.weblinkhttps://pubs.acs.org/doi/pdf/10.1021/acs.orglett.2c04310
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofOrganic Letters
dc.relation.pages671-675
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titleMetal-Free <i>S</i>-Arylation of Phosphorothioate Diesters and Related Compounds with Diaryliodonium Salts
dc.typeJournalArticle
dspace.entity.typePublication