Artykuł w czasopiśmie
Brak miniatury
Licencja
ClosedAccessDostęp zamknięty
 

Amidoboranes of rubidium and caesium: the last missing members of the alkali metal amidoborane family

Uproszczony widok
cris.lastimport.scopus2024-02-12T20:57:17Z
dc.abstract.enWe report the synthesis and physicochemical characterization of two ammonia borane derivatives: rubidium amidoborane (RbNH2BH3) and caesium amidoborane (CsNH2BH3). Both compounds undergo solid-solid phase transition upon heating and then evolve pure hydrogen at temperatures lower than 125 [degree]C. The phase transition is clearly seen in the Raman spectra. We present crystal structures of both low- and high-temperature forms of the title compounds which were solved from powder X-ray data.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorFijałkowski, Karol
dc.contributor.authorLeszczyński, Piotr
dc.contributor.authorJaroń, Tomasz
dc.contributor.authorOwarzany, Rafał
dc.contributor.authorGrochala, Wojciech
dc.date.accessioned2024-01-24T16:28:41Z
dc.date.available2024-01-24T16:28:41Z
dc.date.issued2017
dc.description.financeNie dotyczy
dc.description.number46
dc.description.volume46
dc.identifier.doi10.1039/C7DT03590J
dc.identifier.issn1477-9226
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/100541
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofDalton Transactions
dc.relation.pages16315-16320
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titleAmidoboranes of rubidium and caesium: the last missing members of the alkali metal amidoborane family
dc.typeJournalArticle
dspace.entity.typePublication