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Preparative Electrosynthesis of Strong Oxidizers at Boron‐Doped Diamond Electrode in Anhydrous HF

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cris.lastimport.scopus2024-02-12T20:56:59Z
dc.abstract.enThe first successful electrosynthesis of polycrystalline Ag(II)FBF4 and single crystalline Ag(II)F2 in both galvanostatic and potentiostatic conditions was achieved at the Boron-Doped Diamond electrode in anhydrous hydrogen fluoride. Silver(I) oxidation and the F2 evolution reactions are well separated in the potential scale. Temperature of performing electrosynthesis as well as BF3 overpressure were found to be key variables of the process. Impedance spectroscopy measurements provided insight into the mechanism of formation of silver(II) fluorides pointing out to the presence of HF-soluble Ag(BF4)2 intermediate. The phase purity of the products was determined by X-ray diffraction
dc.affiliationUniwersytet Warszawski
dc.contributor.authorMazej, Zoran
dc.contributor.authorGoreshnik, Evgeny
dc.contributor.authorPołczyński, Piotr
dc.contributor.authorJurczakowski, Rafał
dc.contributor.authorGrochala, Wojciech
dc.contributor.authorGrzelak, Adam
dc.date.accessioned2024-01-25T17:33:52Z
dc.date.available2024-01-25T17:33:52Z
dc.date.issued2019
dc.description.financeNie dotyczy
dc.description.number19
dc.description.volume25
dc.identifier.doi10.1002/CHEM.201806274
dc.identifier.issn0947-6539
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/116968
dc.identifier.weblinkhttp://dx.doi.org/10.1002/chem.201806274
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofChemistry - A European Journal
dc.relation.pages4927-4930
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titlePreparative Electrosynthesis of Strong Oxidizers at Boron‐Doped Diamond Electrode in Anhydrous HF
dc.typeJournalArticle
dspace.entity.typePublication