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Stereodivergent synthesis of alkenes by controllable syn-/anti-fragmentation of β-hydroxysulfonyl intermediates

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cris.lastimport.scopus2024-02-12T20:54:34Z
dc.abstract.enThe reduction of the carbonyl group in acylated trifluoroethyl alkanesulfonates follows the Felkin–Ahn selectivity, and the soformed diastereomeric β-hydroxysulfonyl intermediates undergo syn- and anti-fragmentation, depending on the reaction conditions. In effect, isomeric E- and Z-alkenes are formed in a stereodivergent manner, which mimics the mechanistic manifold of the Peterson olefination.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorGórski, Bartosz
dc.contributor.authorBarbasiewicz, Michał
dc.contributor.authorBasiak, Dariusz
dc.contributor.authorGrzesiński, Łukasz
dc.date.accessioned2024-01-26T08:10:30Z
dc.date.available2024-01-26T08:10:30Z
dc.date.issued2019
dc.description.financeNie dotyczy
dc.description.number33
dc.description.volume17
dc.identifier.doi10.1039/C9OB01563A
dc.identifier.issn1477-0520
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/120726
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofOrganic and Biomolecular Chemistry
dc.relation.pages7660-7663
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titleStereodivergent synthesis of alkenes by controllable syn-/anti-fragmentation of β-hydroxysulfonyl intermediates
dc.typeJournalArticle
dspace.entity.typePublication