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The Influence of Constraints on Gelation in a Controlling/Living Copolymerization Process

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cris.lastimport.scopus2024-02-12T19:34:45Z
dc.abstract.enWe developed a simple model of the copolymerization process in the formation of crosslinked macromolecular systems. A living copolymerization was carried out for free chains, in bulk and in a slit, as well as for grafted chains in a slit. In addition, polymer 2D brushes were placed in a slit with initiator molecules attached to one of the confining walls. Coarse-grained chains were embedded in the vertices of a face-centered cubic lattice with the excluded volume interactions. The simulations of the copolymerization processes were performed using the Dynamic Lattice Liquid algorithm, a version of the Monte Carlo method. The influence of the initial initiator to cross-linker ratio, slit width and grafting on the polymerization and on the gelation was examined. It was also shown that the influence of a confining slit was rather small, while the grafting of chains affected the location of the gel pint significantly.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorSikorski, Andrzej
dc.contributor.authorPolanowski, Piotr
dc.date.accessioned2024-01-26T10:26:06Z
dc.date.available2024-01-26T10:26:06Z
dc.date.issued2023
dc.description.accesstimeAT_PUBLICATION
dc.description.financeNie dotyczy
dc.description.versionFINAL_PUBLISHED
dc.description.volume24
dc.identifier.doi10.3390/IJMS24032701
dc.identifier.issn1422-0067
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/122527
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofInternational Journal of Molecular Sciences
dc.relation.pages2701
dc.rightsCC-BY
dc.sciencecloudnosend
dc.subject.engelation
dc.subject.enconfined space
dc.subject.enMonte-Carlo simulation
dc.subject.enpolymerization
dc.subject.endynamic lattice liquid model
dc.titleThe Influence of Constraints on Gelation in a Controlling/Living Copolymerization Process
dc.typeJournalArticle
dspace.entity.typePublication