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Influence of ligand composition on crystal structure formation : isostructurality and morphotropism.

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cris.lastimport.scopus2024-02-12T19:50:04Z
dc.abstract.enTwo new Ag(i) complexes with 1,3-bis(imidazol-1-ylmethyl)benzene (L1) and 1,3-bis(imidazol-1-ylmethyl)-5-methylbenzene (L2), namely {[AgL1]CF3SO3}n (1) and {[AgL2]CF3SO3}n (2), were synthesised and characterised by SCXRD to uncover the effect that introducing a methyl group to the benzene core of the ligand has on the molecular/crystal structure of the metal complex. The studies revealed a high level of isostructurality of the formed Ag(i) complexes, consisting of 1D cationic chains with the charge neutralised by the counterions applied. These results triggered structural investigations of the parent ligands, which, as revealed by SCXRD, crystallise as dihydrates in different space groups of a monoclinic system. Further analyses revealed that the motifs in their molecular packing in general stay the same. However, some morphotropic/positional adjustments are taking place in L2 to accommodate the presence of the methyl substituent.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorMeervelt, Luc Van
dc.contributor.authorDobrzańska, Liliana
dc.contributor.authorArhangelskis, Mihails
dc.date.accessioned2024-01-25T04:13:52Z
dc.date.available2024-01-25T04:13:52Z
dc.date.issued2021
dc.description.financePublikacja bezkosztowa
dc.description.number2
dc.description.volume23
dc.identifier.doi10.1039/D0CE01302A
dc.identifier.issn1466-8033
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/109254
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofCrystEngComm
dc.relation.pages317-323
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titleInfluence of ligand composition on crystal structure formation : isostructurality and morphotropism.
dc.typeJournalArticle
dspace.entity.typePublication