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Nitro and Other Electron Withdrawing Group Activated Ruthenium Catalysts for Olefin Metathesis Reactions

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cris.lastimport.scopus2024-02-12T19:32:09Z
dc.abstract.enAdvanced applications of the Nobel Prize winning olefin metathesis reaction require user‐friendly and highly universal catalysts. From many successful metathesis catalysts, which belong to the two distinct classes of Schrock and Grubbs‐type catalysts, the subclass of chelating‐benzylidene ruthenium complexes (so‐called Hoveyda–Grubbs catalysts) additionally activated by electron‐withdrawing groups (EWGs) provides a highly tunable platform. In the Review, the origin of the EWG‐activation concept and selected applications of the resulting catalysts in target‐oriented synthesis, medicinal chemistry, as well as in the preparation of fine‐chemicals and in materials chemistry is discussed. Based on the examples, some suggestions for end‐users regarding minimization of catalyst loading, selectivity control, and general optimization of the olefin metathesis reaction are provided.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorKajetanowicz, Anna
dc.contributor.authorGrela, Karol
dc.date.accessioned2024-01-25T13:50:19Z
dc.date.available2024-01-25T13:50:19Z
dc.date.copyright2020-08-18
dc.date.issued2021
dc.description.accesstimeAT_PUBLICATION
dc.description.financeŚrodki finansowe, o których mowa w art. 365 pkt. 2 ustawy
dc.description.number25
dc.description.versionFINAL_PUBLISHED
dc.description.volume60
dc.identifier.doi10.1002/ANIE.202008150
dc.identifier.issn1433-7851
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/113796
dc.identifier.weblinkhttps://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202008150
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofAngewandte Chemie - International Edition
dc.relation.pages13738 - 13756
dc.rightsCC-BY
dc.sciencecloudnosend
dc.subject.enactive pharmaceutic ingredients (APIs)
dc.subject.enolefin metathesis
dc.subject.enprocess optimization
dc.subject.enruthenium catalysts
dc.subject.entotal synthesis
dc.titleNitro and Other Electron Withdrawing Group Activated Ruthenium Catalysts for Olefin Metathesis Reactions
dc.typeJournalArticle
dspace.entity.typePublication