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Study of the 71Π u state of sodium dimer by polarisation labelling spectroscopy

cris.lastimport.scopus2024-02-12T20:02:40Z
dc.abstract.enTwo-colour polarisation labelling experiment measuring excitation spectra of Na2 in the spectral range 34, 600−39, 400 cm−1 has furnished observation of the previously unknown 71Piu electronic state. The excited state is characterised by a set of Dunham coefficients describing the f parity levels up to vibrational level v = 28 and the corresponding potential energy curve is constructed by the inverted perturbation approach method. Molecular parameters determined in the fit include Te = 36583.86 ± 0.03 cm−1, ωe = 107.50 ± 0.03 cm−1 and Re = 3.640 ± 0.001 Å.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorJastrzębski, Włodzimierz
dc.contributor.authorGrochola, Anna
dc.contributor.authorKowalczyk, Paweł
dc.date.accessioned2024-01-26T08:59:09Z
dc.date.available2024-01-26T08:59:09Z
dc.date.issued2022
dc.description.financePublikacja bezkosztowa
dc.identifier.doi10.1080/00268976.2022.2027536
dc.identifier.issn0026-8976
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/120998
dc.identifier.weblinkhttps://www.tandfonline.com/doi/pdf/10.1080/00268976.2022.2027536
dc.languageeng
dc.pbn.affiliationphysical sciences
dc.relation.ispartofMolecular Physics
dc.relation.pagese2027536-1-6
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enlaser spectroscopy
dc.subject.enalkali dimers
dc.subject.enelectronic states
dc.subject.enmolecular constants
dc.subject.enpotential energy curves
dc.titleStudy of the 71Π u state of sodium dimer by polarisation labelling spectroscopy
dc.typeJournalArticle
dspace.entity.typePublication