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Ruthenium Amide Complexes – Synthesis and Catalytic Activity in Olefin Metathesis and in Ring-Opening Polymerisation

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cris.lastimport.scopus2024-02-12T20:01:07Z
dc.abstract.enA set of olefin metathesis catalysts bearing a ruthenium amide moiety was synthesised. In the ruthenium amide form these complexes exhibit very low activity in standard metathesis reactions. However, a dramatic increase of activity was observed upon in situ activation with trimethylsilyl chloride or HCl, allowing successful application of such catalysts in a number of model ring-closing metathesis, cross-metathesis and enyne transformations. Moreover, such activated complexes proved to be very effective catalysts for bulk polymerisation of dicyclopentadiene (DCPD). The influence of factors such as temperature and the nature of additives on the properties of poly-DCPD was examined.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorGawin, Anna
dc.contributor.authorSlugovc, Christian
dc.contributor.authorPump, Eva
dc.contributor.authorKajetanowicz, Anna
dc.contributor.authorGrela, Karol
dc.date.accessioned2024-01-25T19:33:57Z
dc.date.available2024-01-25T19:33:57Z
dc.date.issued2018
dc.description.financeNie dotyczy
dc.description.number16
dc.description.volume2018
dc.identifier.doi10.1002/EJIC.201800251
dc.identifier.issn1434-1948
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/118906
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofEuropean Journal of Inorganic Chemistry
dc.relation.pages1766-1774
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enMetathesis
dc.subject.enRuthenium
dc.subject.enPolymerization
dc.subject.enHomogeneous catalysis
dc.subject.enCarbene ligands
dc.titleRuthenium Amide Complexes – Synthesis and Catalytic Activity in Olefin Metathesis and in Ring-Opening Polymerisation
dc.typeJournalArticle
dspace.entity.typePublication