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Coordination modes of 2-mercapto-1,3-benzothiazolate in gallium and indium complexes

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cris.lastimport.scopus2024-02-12T19:55:12Z
dc.abstract.en2-Mercapto-1,3-benzothiazole (mbztH) may act as a chelating or bridging ligand. In this study, reactions of mbztH with Me3Ga and Me3In were examined. The products were characterized by NMR spectroscopy, elemental analyses, melting point, and molecular weight determinations. Formation of mononuclear chelating complexes Me2M(mbzt) (M = Ga, In) was observed in solutions. Crystallization of Me2M(mbzt) yielded uncommon non-symmetrical dinuclear complexes Me4M2(mbzt)2, in which one metal is bonded to two sulfurs and the other to two nitrogens.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorZiemkowska, Wanda
dc.contributor.authorPindelska, Edyta
dc.contributor.authorOchal, Zbigniew
dc.contributor.authorSocha, Paweł
dc.contributor.authorDobrzycki, Łukasz
dc.contributor.authorBasiak, Dariusz
dc.date.accessioned2024-01-24T20:48:03Z
dc.date.available2024-01-24T20:48:03Z
dc.date.issued2017
dc.description.financeNie dotyczy
dc.description.number9
dc.description.volume70
dc.identifier.doi10.1080/00958972.2017.1313976
dc.identifier.issn0095-8972
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/103742
dc.identifier.weblinkhttp://www.tandfonline.com
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.pages1528-1535
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enGallium
dc.subject.enindium
dc.subject.enthiazoles
dc.subject.en2-Mercapto-1,3-benzothiazole
dc.subject.enchelating ligands
dc.subject.enbridging ligands
dc.titleCoordination modes of 2-mercapto-1,3-benzothiazolate in gallium and indium complexes
dc.typeJournalArticle
dspace.entity.typePublication