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Redox properties of polyelectrolyte multilayer modified electrodes: a significant effect of the interactions between the polyelectrolyte layers in the films

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cris.lastimport.scopus2024-02-12T19:44:52Z
dc.abstract.enThe layer-by-layer (LbL) sequential adsorption of oppositely charged polyelectrolytes leads to the formation of multilayered films (Polyelectrolyte Multilayer, PEM). Such systems may find application as ultrathin membranes with controlled properties. In this paper we examine different polyelectrolyte multilayers formed from poly-L-lysine (PLL), polyethyleneimine (PEI), poly(sodium 4-styrenesulfonate) (PSS) and alginate (ALG) polyelectrolytes. Film thicknesses for the PLL/PSS, PLL/ALG and PEI/PSS combinations showed similar values of up to 14 nm on mica and ca. 22 nm on platinum surfaces. The PEI/ALG combination formed thicker films with thicknesses of up to 90 nm on mica and ca. 140 nm on platinum surfaces. For the prepared films, the electroactive behavior towards [Fe(CN)6]3?/4? and [Ru(NH3)6]3+/2 ions was monitored. We found that the oxidation/reduction current of [Fe(CN)6]3?/4? ions showed three different modes of behavior which can be described as non-permeability, permeability and accumulation of ions. For [Ru(NH3)6]3+/2+ such a relation was not observed and all of the films remained permeable. The permeability of the thin PEMs seems to depend more strongly on the film composition than the film thickness. The best candidate for encapsulation purposes is proposed.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorGranicka, Ludomira
dc.contributor.authorStrawski, Marcin
dc.contributor.authorSzklarczyk, Marek
dc.date.accessioned2024-01-25T19:08:31Z
dc.date.available2024-01-25T19:08:31Z
dc.date.issued2017
dc.description.financeNie dotyczy
dc.description.volume226
dc.identifier.doi10.1016/J.ELECTACTA.2016.12.194
dc.identifier.issn0013-4686
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/118105
dc.identifier.weblinkhttps://www.sciencedirect.com/science/article/pii/S0013468616327669
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofElectrochimica Acta
dc.relation.pages121-131
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enpolyelectrolytes
dc.subject.enPEM thickness
dc.subject.enPEM permeability
dc.subject.enatomic force microscopy
dc.titleRedox properties of polyelectrolyte multilayer modified electrodes: a significant effect of the interactions between the polyelectrolyte layers in the films
dc.typeJournalArticle
dspace.entity.typePublication