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Design and construction of the imidazole-2-thione-based copper(I) complexes by varying the co-anion and synthesis conditions and verifying their antimicrobial activity

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cris.lastimport.scopus2024-02-12T19:47:52Z
dc.abstract.enA series of copper-based polymers of [Cu(bbit)I]n (1), {[Cu(bbit)2](HSO4).(S8)0.5}n (2), [Cu4(CN)4 (bbit)2]n (3) and [Cu(bbit)Cl]n (4) have been designed and synthesized from reaction of CuX (X ​= ​I, Cl and CN) with 1,1-(1,4-butanediyl) bis (1,3-dihydro-3-methyl-1H-imidazole- 2-thione) (bbit) ligand. These compounds were characterized by IR, CHNS, PL, TGA, PXRD and their crystal structures were determined by X-ray crystallography. The final structure of synthesized polymers was affected by applied co-ligand and reaction conditions. Treating copper(I) iodide with equimolar ratio of bbit ligand afforded 1D wavelike polymer 1 with a distorted trigonal planar geometry by branched tube method. Polymer 2 has synthesized by the same starting material for 1 through unexpected process by solvothermal method with a distorted S4 tetrahedral environment. With addition of CN− to the reaction mixture of 1, 2D wavelike polymer of 3 with distorted trigonal CNS and tetrahedral CNS2 coordination environments was formed. Polymer 4 is analogue of 1 and was prepared by the same method as for 1 using copper chloride instead of copper iodide. The action of the title polymers on several pathogens were verified via antibacterial, MIC and MBC tests. The obtained results displayed that the polymers 1, 2 and 4 have bactericidal behavior, while the polymer 3 is a bacteriostatic agent.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorGajda, Roman
dc.contributor.authorMotamedi, Hossein
dc.contributor.authorNozarian, Kimia
dc.contributor.authorMousavifard, Elham Sadat
dc.contributor.authorAbrahams, Carmel T.
dc.contributor.authorMayer, Peter
dc.contributor.authorWoźniak, Krzysztof
dc.contributor.authorBeheshti, Azizolla
dc.date.accessioned2024-01-24T21:33:16Z
dc.date.available2024-01-24T21:33:16Z
dc.date.issued2021
dc.description.financePublikacja bezkosztowa
dc.description.volume294
dc.identifier.doi10.1016/J.JSSC.2020.121874
dc.identifier.issn0022-4596
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/104589
dc.identifier.weblinkhttps://api.elsevier.com/content/article/PII:S0022459620307052?httpAccept=text/xml
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofJournal of Solid State Chemistry
dc.relation.pages121874
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enImidazole-2-thione ligand
dc.subject.enCopper coordination compounds
dc.subject.enSynthesis procedure
dc.subject.enAntibacterial activity
dc.subject.enBranched tube
dc.subject.enSolvothermal
dc.titleDesign and construction of the imidazole-2-thione-based copper(I) complexes by varying the co-anion and synthesis conditions and verifying their antimicrobial activity
dc.typeJournalArticle
dspace.entity.typePublication