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Enabling Fast Pseudo-2D NMR Spectral Acquisition for Broadband Homonuclear Decoupling: The EXACT NMR Approach

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dc.abstract.enPseudo-2D NMR spectroscopy provides a means of acquiring broadband homonuclear decoupled spectra useful for structural characterization of complex molecules. However, data points concatenated in the direct dimension in these experiments are acquired over incremented time periods—leading to long acquisition times with no sensitivity benefits due to the absence of signal averaging between scans. Herein, the concept of EXACT NMR spectroscopy (“burst” non-uniform sampling of data points) is explored in pseudo-2D experiments with results revealing little or no loss in spectral quality or signal intensity despite the acceleration of acquisition—up to 400 % in some cases.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorKazimierczuk, Krzysztof
dc.contributor.authorButts, Craig P.
dc.contributor.authorCobas, Carlos
dc.contributor.authorZorin, Vadim
dc.contributor.authorNdukwe, Ikenna E.
dc.contributor.authorShchukina, Alexandra
dc.date.accessioned2024-01-24T22:47:27Z
dc.date.available2024-01-24T22:47:27Z
dc.date.issued2017
dc.description.financeNie dotyczy
dc.identifier.doi10.1002/CPHC.201700474
dc.identifier.issn1439-4235
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/106153
dc.pbn.affiliationchemical sciences
dc.relation.ispartofChemPhysChem
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enEXACT homonuclear decoupling non-uniform sampling pseudo-2D NMR spectroscopy pure shift
dc.titleEnabling Fast Pseudo-2D NMR Spectral Acquisition for Broadband Homonuclear Decoupling: The EXACT NMR Approach
dc.typeJournalArticle
dspace.entity.typePublication