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Evidence for a photoinduced isonitrosyl isomer in ruthenium dinitrosyl compounds

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dc.abstract.enSince the seminal characterisation of two photoinduced linkage isomers (PLIs) in crystals of sodium nitroprusside dihydrate Na2ijFeIJCN)5IJNO)]·2H2O by photocrystallography, this phenomenon has been described in a large variety of molecular mononitrosyl complexes. The two photoinduced metastable isomers consist of a κO, isonitrosyl, binding mode (MS1) and a κ2N,O, side-on, binding mode (MS2). We have recently detected by infrared spectroscopy various PLI states in dinitrosyl ruthenium complexes, for which only κN binding modes were characterised by photocrystallography. We provide here experimental evidence for a photoinduced isonitrosyl isomer in the [RuIJPCy3)2IJNO)2Cl]BF4 (Cy = cyclohexyl) complex salt, the results being strongly supported by DFT calculations.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorBoukheddaden, Kamel
dc.contributor.authorBouchez, Guillaume
dc.contributor.authorGallien, Anna K.E.
dc.contributor.authorWoike, Theo
dc.contributor.authorKutniewska, Sylwia Ewa
dc.contributor.authorKlüfers, Peter
dc.contributor.authorKamiński, Radosław
dc.contributor.authorSchaniel, Dominik
dc.contributor.authorPillet, Sébastien
dc.contributor.authorBendeif, El-Eulmi
dc.contributor.authorCasaretto, Nicolas
dc.date.accessioned2024-01-24T23:39:05Z
dc.date.available2024-01-24T23:39:05Z
dc.date.issued2019
dc.description.financeNie dotyczy
dc.description.number38
dc.description.volume21
dc.identifier.doi10.1039/C9CE01119F
dc.identifier.issn1466-8033
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/106583
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofCrystEngComm
dc.relation.pages5804-5810
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titleEvidence for a photoinduced isonitrosyl isomer in ruthenium dinitrosyl compounds
dc.typeJournalArticle
dspace.entity.typePublication