Artykuł w czasopiśmie
Brak miniatury
Licencja
CC-BY-NCCC-BY-NC - Uznanie autorstwa - Użycie niekomercyjne
 

Physico-chemical study of new supramolecular-architectured hybrid organic–inorganic sulfates incorporating diammoniumdiphenylsulfone cations

Uproszczony widok
dc.abstract.enTwo new hybrid organic-inorganic compounds, which incorporate 3,3′-diammoniumdiphenylsulfone or 4,4′-diammoniumdiphenylsulfone cations and sulfate anions, were synthesized and analyzed in detail. The crystal structures of both systems were established using single-crystal X-ray diffraction analysis. Crystallographic study revealed that the crystals of both investigated compounds were constructed of repeatedly occurring organic and inorganic layers and allowed the description of their structural features. Dense networks of N-H⋯O hydrogen bonds were found in both crystals. In addition, S-O⋯π contacts and weak C-H⋯O hydrogen bonds were identified in each analyzed crystal network. All intermolecular interactions were quantitatively described by Hirshfeld surface analysis. Furthermore, a13C NMR study was conducted for the grown crystals. The functional groups present in the titular compounds were also the subjects of IR and Raman spectral studies. Finally, TGA/DSC and UV-vis absorption measurements were performed and allowed the thermal and optical characterization of the titular materials.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorWróbel, Agata
dc.contributor.authorMahroug, Adel
dc.contributor.authorTrzybiński, Damian
dc.contributor.authorBouguerra, Manel
dc.contributor.authorWoźniak, Krzysztof
dc.contributor.authorBelhouchet, M.
dc.date.accessioned2024-01-25T16:37:34Z
dc.date.available2024-01-25T16:37:34Z
dc.date.copyright2021-08-02
dc.date.issued2021
dc.description.accesstimeAT_PUBLICATION
dc.description.financePublikacja bezkosztowa
dc.description.number42
dc.description.versionFINAL_PUBLISHED
dc.description.volume11
dc.identifier.doi10.1039/D1RA03696C
dc.identifier.issn2046-2069
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/115892
dc.identifier.weblinkhttp://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA03696C
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofRSC Advances
dc.relation.pages26368-26378
dc.rightsCC-BY-NC
dc.sciencecloudnosend
dc.titlePhysico-chemical study of new supramolecular-architectured hybrid organic–inorganic sulfates incorporating diammoniumdiphenylsulfone cations
dc.typeJournalArticle
dspace.entity.typePublication