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Open versus Interpenetrated: Switchable Supramolecular Trajectories in Mechanosynthesis of a Halogen-Bonded Borromean Network

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cris.lastimport.scopus2024-02-12T19:38:30Z
dc.abstract.enPrecise control over topologically intricate molecular architectures remains an open challenge for chemists due to their inherent structural complexity. We report a simple solvent-free strategy to selectively prepare two multi-component supramolecular crystalline systems based on the halogen bond, endowed with either an unknot topology or a Borromean-type entanglement. Real-time in situ monitoring of the solvent-free mechanochemical synthesis of these three-component halogen-bonded ionic co-crystals reveals that the choice of milling conditions leads to a switch in the supramolecular reaction trajectory, resulting in the selective formation of an open halogen-bonded network or a halogen-bonded Borromean-type assembly.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorMetrangolo, Pierangelo
dc.contributor.authorUrsini, Maurizio
dc.contributor.authorCametti, Massimo
dc.contributor.authorMartí-Rujas, Javier
dc.contributor.authorFriščić, Tomislav
dc.contributor.authorResnati, Giuseppe
dc.contributor.authorTerraneo, Giancarlo
dc.contributor.authorArhangelskis, Mihails
dc.contributor.authorCatalano, Luca
dc.contributor.authorGermann, Luzia S.
dc.contributor.authorHalasz, Ivan
dc.contributor.authorUžarević, Krunoslav
dc.contributor.authorEtter, Martin
dc.contributor.authorDinnebier, Robert E.
dc.contributor.authorJulien, Patrick A.
dc.date.accessioned2024-01-25T15:55:26Z
dc.date.available2024-01-25T15:55:26Z
dc.date.issued2021
dc.description.financePublikacja bezkosztowa
dc.description.number1
dc.description.sdgAffordableAndCleanEnergy
dc.description.volume7
dc.identifier.doi10.1016/J.CHEMPR.2020.10.022
dc.identifier.issn2451-9308
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/114916
dc.identifier.weblinkhttps://api.elsevier.com/content/article/PII:S245192942030543X?httpAccept=text/xml
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofChem
dc.relation.pages146-154
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enball milling
dc.subject.enborromean rings
dc.subject.encrystal engineering
dc.subject.endiiodoperfluoroalkanes
dc.subject.enhalogen bond
dc.subject.enmechanochemistry
dc.subject.enpolymorph
dc.subject.enSDG3: Good health and well-being
dc.subject.enSDG7: Affordable and clean energy
dc.subject.enSDG9: Industry, innovation, and infrastructure
dc.subject.enself-assembly
dc.subject.ensolvent-free synthesis
dc.subject.ensupramolecular chemistry
dc.titleOpen versus Interpenetrated: Switchable Supramolecular Trajectories in Mechanosynthesis of a Halogen-Bonded Borromean Network
dc.typeJournalArticle
dspace.entity.typePublication