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Triggering the Shrinking/Swelling Process in Thin Gel Layers on Conducting Surfaces by Applying an Appropriate Potential

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dc.abstract.enNegatively charged, pH-sensitive, very thin gel layers with accumulated hexaammineruthenium (II)/(III) were deposited on conducting surfaces. The gel was synthesized by applying an electrochemically induced freeradical polymerization method. This method allowed covering the electrode surface with an uniform and compact layer. The modified electrodes exhibited excellent current switch on/off behavior in response to changes in pH. However, the main goal of this study was to achieve the control of the layer thickness by changing the oxidation state of hexaammineruthenium. The layers could be reversibly swollen/shrinked by applying appropriate potentials.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorStojek, Zbigniew
dc.contributor.authorGawrońska, Andżelika
dc.contributor.authorKarbarz, Marcin
dc.contributor.authorMarcisz, Kamil
dc.date.accessioned2024-01-26T11:06:50Z
dc.date.available2024-01-26T11:06:50Z
dc.date.issued2019
dc.description.financeNie dotyczy
dc.description.number12
dc.description.volume11
dc.identifier.doi10.1021/ACSAMI.9B00713
dc.identifier.issn1944-8244
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/123809
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofACS Applied Materials & Interfaces
dc.relation.pages12114-12120
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enthin gel films
dc.subject.enpoly(sodium acrylate)
dc.subject.enelectroresponsive hydrogel layers
dc.subject.enhexaammineruthenium (II)/(III)
dc.subject.envolume phase transition
dc.subject.enON−OFF switch behavior
dc.titleTriggering the Shrinking/Swelling Process in Thin Gel Layers on Conducting Surfaces by Applying an Appropriate Potential
dc.typeJournalArticle
dspace.entity.typePublication