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Visible-light-promoted alkylation of unsaturated MIDA boronates using Ru(bpy) 3 Cl 2 as the photoredox catalyst

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dc.abstract.enThe development of a visible light-mediated atom transfer radical addition (ATRA) of perfluoroalkyl iodides to ethynyl-, vinyl- and allyl-MIDA boronates using the reductive and oxidative quenching of [Ru(bpy)3]Cl2 is described. Using an operationally simple and mild protocol, the corresponding MIDA boronates containing perfluoroalkyl groups were obtained in moderate to high yields. The structures of three products were confirmed by single crystal X-ray diffraction studies.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorKliś, Tomasz
dc.contributor.authorSerwatowski, Janusz
dc.contributor.authorDąbrowski, Marek
dc.contributor.authorDurka, Krzysztof
dc.contributor.authorKublicki, Marcin
dc.contributor.authorWoźniak, Krzysztof
dc.date.accessioned2024-01-26T11:49:26Z
dc.date.available2024-01-26T11:49:26Z
dc.date.issued2017
dc.description.financeNie dotyczy
dc.description.number22
dc.description.volume58
dc.identifier.doi10.1016/J.TETLET.2017.04.075
dc.identifier.issn0040-4039
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/124664
dc.identifier.weblinkhttp://www.sciencedirect.com/science/article/pii/S0040403917305300
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofTetrahedron Letters
dc.relation.pages2162-2165
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enMIDA boronates
dc.subject.enPhotoredox catalysis
dc.subject.enPerfluorohaloalkanes
dc.subject.enATRA
dc.titleVisible-light-promoted alkylation of unsaturated MIDA boronates using Ru(bpy) 3 Cl 2 as the photoredox catalyst
dc.typeJournalArticle
dspace.entity.typePublication