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Design and Self-Assembling Behaviour of Calamitic Reactive Mesogens with Lateral Methyl and Methoxy Substituents and Vinyl Terminal Group

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cris.lastimport.scopus2024-02-12T20:43:11Z
dc.abstract.enSmart self-organising systems attract considerable attention in the scientific community. In order to control and stabilise the liquid crystalline behaviour, and hence the self-organisation, the polymerisation process can be effectively used. Mesogenic units incorporated into the backbones as functional side chains of weakly cross-linked macromolecules can become orientationally ordered. Several new calamitic reactive mesogens possessing the vinyl terminal group with varying flexible chain lengths and with/without lateral substitution by the methyl (methoxy) groups have been designed and studied. Depending on the molecular structure, namely, the type and position of the lateral substituents, the resulting materials form the nematic, the orthogonal SmA and the tilted SmC phases in a reasonably broad temperature range, and the structure of the mesophases was confirmed by X-ray diffraction experiments. The main objective of this work is to contribute to better understanding of the molecular structure–mesomorphic property relationship for new functional reactive mesogens, aiming at further design of smart self-assembling macromolecular materials for novel sensor systems.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorPociecha, Damian
dc.contributor.authorCigl, Martin
dc.contributor.authorBubnov, Alexej
dc.contributor.authorOtruba, Marek
dc.contributor.authorHamplová, Věra
dc.contributor.authorChen, Hsiu-Hui
dc.contributor.authorPenkov, Deyvid
dc.date.accessioned2024-01-24T21:33:23Z
dc.date.available2024-01-24T21:33:23Z
dc.date.copyright2021-06-30
dc.date.issued2021
dc.description.accesstimeAT_PUBLICATION
dc.description.financePublikacja bezkosztowa
dc.description.number13
dc.description.versionFINAL_PUBLISHED
dc.description.volume13
dc.identifier.doi10.3390/POLYM13132156
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/104597
dc.identifier.weblinkhttps://www.mdpi.com/2073-4360/13/13/2156/pdf
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofPolymers
dc.relation.pagesart.no. 2156
dc.rightsCC-BY
dc.sciencecloudnosend
dc.subject.enLiquid crystal
dc.subject.enReactive mesogen
dc.subject.enSelf-assembling behaviour
dc.subject.enSmectic phases
dc.subject.enVinyl group
dc.titleDesign and Self-Assembling Behaviour of Calamitic Reactive Mesogens with Lateral Methyl and Methoxy Substituents and Vinyl Terminal Group
dc.typeJournalArticle
dspace.entity.typePublication