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Strategies for the Preparation of Phosphorus Janus Dendrimers and Their Properties

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dc.abstract.enDendrimers, being highly branched monodispersed macromolecules, predominantly exhibit identical terminal functionalities within their structural framework. Nonetheless, there are instances where the presence of two distinct surface functionalities becomes advantageous for the fulfilment of specific properties. To achieve this objective, one approach involves implementing Janus dendrimers, consisting of two dendrimeric wedges terminated by dissimilar functionalities. The prevalent method for creating these structures involves the synthesis of dendrons that possess a core functionality that complements that of a second dendron, facilitating their coupling to generate the desired dendrimers. In this comprehensive review, various techniques employed in the fabrication of phosphorus-based Janus dendrimers are elucidated, displaying the different coupling methodologies employed between the two units. The advantages of phosphorus dendrimers over classic dendrimers will be shown, as the presence of at least one phosphorus atom in each generation allows for the easy monitoring of reactions and the confirmation of purity through a simple technique such as 31P NMR, as these structures typically exhibit easily interpretable patterns.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorSebastián, Rosa María
dc.contributor.authorCaminade, Anne-Marie
dc.contributor.authorGrela, Karol
dc.contributor.authorKajetanowicz, Anna
dc.contributor.authorCejas-Sánchez, Joel
dc.date.accessioned2024-01-26T08:19:45Z
dc.date.available2024-01-26T08:19:45Z
dc.date.copyright2023-02-21
dc.date.issued2023
dc.description.accesstimeAT_PUBLICATION
dc.description.financeNie dotyczy
dc.description.number14
dc.description.versionFINAL_PUBLISHED
dc.description.volume28
dc.identifier.doi10.3390/MOLECULES28145570
dc.identifier.issn1420-3049
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/120795
dc.identifier.weblinkhttps://www.mdpi.com/1420-3049/28/14/5570/pdf
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofMolecules
dc.relation.pages5570
dc.rightsCC-BY
dc.sciencecloudnosend
dc.subject.enphosphorus chemistry
dc.subject.enJanus dendrimers
dc.subject.endendrons
dc.subject.en31P NMR spectroscopy
dc.titleStrategies for the Preparation of Phosphorus Janus Dendrimers and Their Properties
dc.typeJournalArticle
dspace.entity.typePublication