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Corey−Chaykovsky Cyclopropanation of Nitronaphthalenes: Access to Benzonorcaradienes and Related Systems

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cris.lastimport.scopus2024-02-12T20:45:32Z
dc.abstract.enNitronaphthalene derivatives react as Michael acceptors in the Corey−Chaykovsky reaction with alkyl phenyl selenones and alkyl diphenyl sulfonium salts. Mechanistic studies reveal that sterically demanding substituents at the carbanionic center favor formation of cyclopropanes and suppress competitive β- elimination to the alkylated products. The transformation, demonstrated also on heterocyclic nitroquinoline and nitroindazolines, is an example of transition metalfree dearomatization method.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorAntoniak, Damian
dc.contributor.authorBarbasiewicz, Michał
dc.date.accessioned2024-01-24T20:48:24Z
dc.date.available2024-01-24T20:48:24Z
dc.date.issued2019
dc.description.financeNie dotyczy
dc.description.number23
dc.description.volume21
dc.identifier.doi10.1021/ACS.ORGLETT.9B03375
dc.identifier.issn1523-7060
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/103766
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofOrganic Letters
dc.relation.pages9320-9325
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titleCorey−Chaykovsky Cyclopropanation of Nitronaphthalenes: Access to Benzonorcaradienes and Related Systems
dc.typeJournalArticle
dspace.entity.typePublication