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W-shaped mesogens and variations of their molecular structure

dc.abstract.enNew bent-core liquid crystalline dimers with W-shaped molecular geometry have been prepared and studied. We have modified the dimer shape by variation of the connecting part between two bent-core units and changing the terminal chains (perfluoroalkyl, siloxanealkyl). Additionally, we have altered the inner bend angle value (120°, 60° and 148°) by utilization of different aromatic units. Mesomorphic properties of new dimers were established based on the texture observation in the polarizing microscope and DSC measurements. Moreover, x-ray structural analysis has been performed for selected dimers to confirm phase identification. For most of the studied dimers, nematic or columnar phases have been detected, for several compounds appearing in a nematiccolumnar phase sequence on cooling from the isotropic phase. The studied dimers showed richer polymorphism than their monomeric counterparts.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorPociecha, Damian
dc.contributor.authorHorčic, Martin
dc.contributor.authorSvoboda, Jiří
dc.contributor.authorNovotná, Vladimíra
dc.date.accessioned2024-01-26T12:07:58Z
dc.date.available2024-01-26T12:07:58Z
dc.date.issued2019
dc.description.financeNie dotyczy
dc.description.number5
dc.description.volume46
dc.identifier.doi10.1080/02678292.2019.1573328
dc.identifier.issn0267-8292
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/125331
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofLiquid Crystals
dc.relation.pages816-824
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enBent-core liquid crystals
dc.subject.enW-shaped mesogens
dc.subject.endimers
dc.subject.enmesomorphic properties
dc.titleW-shaped mesogens and variations of their molecular structure
dc.typeJournalArticle
dspace.entity.typePublication