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Fe III 48 ‐Containing 96‐Tungsto‐16‐Phosphate: Synthesis, Structure, Magnetism and Electrochemistry

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dc.abstract.enThe 48-FeIII-containing 96-tungsto-16-phosphate, [FeIII 48(OH)76(H2O)16(HP2W12O48)8]36@ (Fe48), has been ynthesized and structurally characterized. This polyanion comprises eight equivalent {FeIII 6P2W12} units that are linked in an end-on fashion forming a macrocyclic assembly that contains more iron centers than any other hlyoxometalate (POM) known to date. The novel Fe48 was synthesized by a simple one-pot reaction of an {Fe22} coordination complex with the hexalacunary {P2W12} POM precursor in water. The title polyanion was characterized by single-crystal XRD, FTIR, TGA, magnetic and electrochemical studies.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorBindra, Jasleen K.
dc.contributor.authorBassil, Bassem S.
dc.contributor.authorKortz, Ulrich
dc.contributor.authorDalal, Naresh S.
dc.contributor.authorGoura, Joydeb
dc.contributor.authorRutkowska, Iwona
dc.contributor.authorKulesza, Paweł
dc.date.accessioned2024-01-25T00:40:11Z
dc.date.available2024-01-25T00:40:11Z
dc.date.copyright2020-11-03
dc.date.issued2020
dc.description.accesstimeAT_PUBLICATION
dc.description.financePublikacja bezkosztowa
dc.description.number68
dc.description.versionFINAL_PUBLISHED
dc.description.volume26
dc.identifier.doi10.1002/CHEM.202002832
dc.identifier.issn0947-6539
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/107082
dc.identifier.weblinkhttps://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fchem.202002832
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofChemistry - A European Journal
dc.relation.pages15821-15824
dc.rightsCC-BY
dc.sciencecloudnosend
dc.subject.enelectrochemistry · iron · macrocycle · magnetism · polyoxometalates
dc.titleFe III 48 ‐Containing 96‐Tungsto‐16‐Phosphate: Synthesis, Structure, Magnetism and Electrochemistry
dc.typeJournalArticle
dspace.entity.typePublication