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N-Heterocyclic Carbene-Catalyzed Olefination of Aldehydes with Vinyliodonium Salts To Generate α,β-Unsaturated Ketones

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dc.abstract.enAn organocatalyzed metal-free, direct olefination of aldehydes with vinyliodonium salts has been achieved by an N-heterocyclic carbene-promoted C–H bond activation. The reaction proceeds under very mild conditions, delivering a range of (hetero)aryl-vinyl ketones in good yields. The retention of the double bond configuration is uniformly observed, and the application of 2-methoxyphenyl auxiliary group in iodonium salts secures a complete selectivity of the vinyl transfer.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorKałek, Marcin
dc.contributor.authorRajkiewicz, Adam
dc.date.accessioned2024-01-25T13:49:13Z
dc.date.available2024-01-25T13:49:13Z
dc.date.issued2018
dc.description.financeNie dotyczy
dc.description.volume20
dc.identifier.doi10.1021/ACS.ORGLETT.8B00447
dc.identifier.issn1523-7060
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/113646
dc.identifier.weblinkhttps://doi.org/10.1055/s-0037-1609639
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofOrganic Letters
dc.relation.pages1906-1909
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.en2018 Kałek
dc.titleN-Heterocyclic Carbene-Catalyzed Olefination of Aldehydes with Vinyliodonium Salts To Generate α,β-Unsaturated Ketones
dc.typeReviewArticle
dspace.entity.typePublication