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Dostęp zamknięty183W nuclear dipole moment determined by gas-phase NMR spectroscopy
| cris.lastimport.scopus | 2024-02-12T20:48:39Z |
| dc.abstract.en | The magnetic dipole moment of the tungsten-183 nucleus, µ(183W), is determined from measurements of gas-phase 183W nuclear magnetic resonance of tungsten hexafluoride dissolved in CF4. The tungsten-183 resonance frequency combined with recently reported computations of the magnetic shielding of the 183W nucleus in WF6 (Ruud et al., 2014) yields μ(183W) = 0.116953(18) μN. Moreover, it is found that the gas-to-liquid shifts of nuclear shielding for WF6 are ΔσGL(19F) = −6.9 ppm and ΔσGL(183W) = −18.4 ppm. The spin–spin coupling 1J(183W,19F) is 43.75(24) Hz for liquid WF6. |
| dc.affiliation | Uniwersytet Warszawski |
| dc.contributor.author | Garbacz, Piotr |
| dc.contributor.author | Makulski, Włodzimierz |
| dc.date.accessioned | 2024-01-24T15:35:19Z |
| dc.date.available | 2024-01-24T15:35:19Z |
| dc.date.issued | 2017 |
| dc.description.finance | Nie dotyczy |
| dc.description.volume | 498–499 |
| dc.identifier.doi | 10.1016/J.CHEMPHYS.2017.10.003 |
| dc.identifier.issn | 0301-0104 |
| dc.identifier.uri | https://repozytorium.uw.edu.pl//handle/item/100018 |
| dc.language | eng |
| dc.pbn.affiliation | chemical sciences |
| dc.relation.ispartof | Chemical Physics |
| dc.relation.pages | 7-11 |
| dc.rights | ClosedAccess |
| dc.sciencecloud | nosend |
| dc.title | 183W nuclear dipole moment determined by gas-phase NMR spectroscopy |
| dc.type | JournalArticle |
| dspace.entity.type | Publication |