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Photostable orange-red fluorescent unsymmetrical diketopyrrolopyrrole–BF2 hybrids

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dc.abstract.enThe straightforward synthesis of structurally unique DPP–BODIPY hybrids has been developed using unsymmetrical, imidazopyridine substituted DPPs. These hybrids exhibit a superb combination of photophysical properties including high photostability, good fluorescence quantum yield as well as markedly bathochromically shifted absorption and emission compared to conventional diketopyrrolopyrroles. Increasing the size of the imidazopyridine substituent and/or the electron donating power of the other aryl substituent can further redshift both absorption and emission to reach ∼650 nm for the free-base and ca. 700 nm for boron-chelates. A strong intramolecular hydrogen bond is responsible for the small change in geometry between the ground and excited states and hence relatively small differences in photophysical properties upon formation of boron-chelates are observed. The solvent dependence of the photophysical properties for the free base and DPP–BF2 complexes were investigated and show strong fluorescence with long lifetimes in both non-polar and polar aprotic environments.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorTASIOR, Mariusz
dc.contributor.authorLaurent, Adèle D.
dc.contributor.authorGryko, Daniel
dc.contributor.authorJacquemin, Denis
dc.contributor.authorYoung, David
dc.contributor.authorTkachenko, Nikolai
dc.contributor.authorDobrzycki, Łukasz
dc.contributor.authorCyrański, Michał
dc.date.accessioned2024-01-25T16:37:04Z
dc.date.available2024-01-25T16:37:04Z
dc.date.issued2020
dc.description.financePublikacja bezkosztowa
dc.description.number23
dc.description.volume8
dc.identifier.doi10.1039/D0TC01202E
dc.identifier.issn2050-7534
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/115860
dc.identifier.weblinkhttp://pubs.rsc.org/en/content/articlepdf/2020/TC/D0TC01202E
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofJournal of Materials Chemistry C
dc.relation.pages7708-7717
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titlePhotostable orange-red fluorescent unsymmetrical diketopyrrolopyrrole–BF2 hybrids
dc.typeJournalArticle
dspace.entity.typePublication