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Synthesis of Phenol-Tagged Ruthenium Alkylidene Olefin Metathesis Catalysts for Robust Immobilisation Inside Metal–Organic Framework Support

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dc.abstract.enTwo new unsymmetrical N-heterocyclic carbene ligand (uNHC)-based ruthenium complexes featuring phenolic OH function were obtained and fully characterised. The more active one was then immobilised on the metal–organic framework (MOF) solid support (Al)MIL-101-NH2. The catalytic activity of such a heterogeneous system was tested, showing that, while the heterogeneous catalyst is less active than the corresponding homogeneous catalyst in solution, it can catalyse selected olefin metathesis reactions, serving as the proof-of-concept for the immobilisation of catalytically active complexes in MOFs using a phenolic tag.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorNadirova, Mariana
dc.contributor.authorGrela, Karol
dc.contributor.authorKajetanowicz, Anna
dc.contributor.authorChmielewski, Michał
dc.contributor.authorWiszniewski, Marcin
dc.contributor.authorSebastián, Rosa María
dc.contributor.authorCejas-Sánchez, Joel
dc.date.accessioned2024-01-26T09:26:53Z
dc.date.available2024-01-26T09:26:53Z
dc.date.copyright2023-01-28
dc.date.issued2023
dc.description.accesstimeAT_PUBLICATION
dc.description.financeNie dotyczy
dc.description.number2
dc.description.versionFINAL_PUBLISHED
dc.description.volume13
dc.identifier.doi10.3390/CATAL13020297
dc.identifier.issn2073-4344
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/121313
dc.identifier.weblinkhttps://www.mdpi.com/2073-4344/13/2/297/pdf
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofCatalysts
dc.relation.pages297
dc.rightsCC-BY
dc.sciencecloudnosend
dc.subject.enimmobilisation
dc.subject.enmetal–organic framework (MOF)
dc.subject.enolefin metathesis
dc.subject.enruthenium
dc.titleSynthesis of Phenol-Tagged Ruthenium Alkylidene Olefin Metathesis Catalysts for Robust Immobilisation Inside Metal–Organic Framework Support
dc.typeJournalArticle
dspace.entity.typePublication