Artykuł w czasopiśmie
Brak miniatury
Licencja
CC-BY-NCCC-BY-NC - Uznanie autorstwa - Użycie niekomercyjne
 

Synthesis and structural, electrochemical and photophysical studies of triferrocenyl-substituted 1,3,5-triphenylbenzene: a cyan-light emitting molecule showing aggregation-induced enhanced emission

Uproszczony widok
dc.abstract.enTriferrocenyl-substituted 1,3,5-triphenylbenzene was successfully synthesized in high yield. Single-crystal X-ray diffraction experiments revealed that the internal rotations of the ferrocenyl moieties are significantly restricted in the solid phase and that there are no significant π stacking interactions therein. The photoluminescence of the crystals is essentially the same as that of dilute chloroform solutions. However, studies of this cyan-light emitting substance in mixtures of chloroform and methanol revealed the aggregation-induced enhanced emission (AIEE) feature that boosts its fluorescence quantum yield from 13% up to 74%. We demonstrate the AIEE effect for a new class of easy-to-prepare aromatic molecules containing several metallocene units for the first time.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorGuńka, Piotr A.
dc.contributor.authorKasprzak, Artur
dc.contributor.authorNowicka, Anna
dc.contributor.authorKowalczyk, Agata
dc.date.accessioned2024-01-26T09:26:32Z
dc.date.available2024-01-26T09:26:32Z
dc.date.copyright2020-10-07
dc.date.issued2020
dc.description.accesstimeAT_PUBLICATION
dc.description.financePublikacja bezkosztowa
dc.description.number42
dc.description.versionFINAL_PUBLISHED
dc.description.volume49
dc.identifier.doi10.1039/D0DT02948C
dc.identifier.issn1477-9226
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/121289
dc.identifier.weblinkhttps://pubs.rsc.org/en/content/articlelanding/2020/DT/D0DT02948C#!divAbstract
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofDalton Transactions
dc.relation.pages14807-14814
dc.rightsCC-BY-NC
dc.sciencecloudnosend
dc.titleSynthesis and structural, electrochemical and photophysical studies of triferrocenyl-substituted 1,3,5-triphenylbenzene: a cyan-light emitting molecule showing aggregation-induced enhanced emission
dc.typeJournalArticle
dspace.entity.typePublication