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Light-Responsive Supramolecular Nanotubes-Based Chiral Plasmonic Assemblies

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cris.lastimport.scopus2024-02-12T20:36:38Z
dc.abstract.enWe describe the fabrication of dual-responsive (thermo/light) chiral plasmonic films. The idea is based on using photoswitchable achiral liquid crystal (LCs) forming chiral nanotubes for templating helical assemblies of Au NPs. Circular dichroism spectroscopy (CD) confirms chiroptical properties coming from the arrangement of organic and inorganic components, with up to 0.2 dissymmetry factor (g-factor). Upon exposure to UV light, organic molecules isomerize, resulting in controlled melting of organic nanotubes and/or inorganic nanohelices. The process can be reversed using visible light and further modified by varying the temperature, offering a control of chiroptical response of the composite material. These properties can play a key role in the future development of chiral plasmonics, metamaterials, and optoelectronic devices.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorWójcik, Michał
dc.contributor.authorLewandowski, Wiktor
dc.contributor.authorGórecka, Ewa
dc.contributor.authorPawlak, Mateusz
dc.contributor.authorJędrych, Agnieszka
dc.date.accessioned2024-01-25T05:10:44Z
dc.date.available2024-01-25T05:10:44Z
dc.date.copyright2023-03-10
dc.date.issued2023
dc.description.accesstimeAT_PUBLICATION
dc.description.financeNie dotyczy
dc.description.number6
dc.description.versionFINAL_PUBLISHED
dc.description.volume17
dc.identifier.doi10.1021/ACSNANO.2C10955
dc.identifier.issn1936-0851
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/111238
dc.identifier.weblinkhttps://pubs.acs.org/doi/pdf/10.1021/acsnano.2c10955
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofACS Nano
dc.relation.pages5548-5560
dc.rightsCC-BY
dc.sciencecloudnosend
dc.subject.enliquid crystals
dc.subject.ennanocomposites
dc.subject.enorganic nanotubes
dc.subject.enphotoswitchability
dc.subject.enplasmonic nanoparticles
dc.subject.enreversibly reconfigurable assembly
dc.subject.ensupramolecular self-assembly
dc.titleLight-Responsive Supramolecular Nanotubes-Based Chiral Plasmonic Assemblies
dc.typeJournalArticle
dspace.entity.typePublication