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Ruthenium Olefin Metathesis Catalysts Systematically Modified in Chelating Benzylidene Ether Fragment: Experiment and Computations

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cris.lastimport.scopus2024-02-12T20:37:00Z
dc.abstract.enFive Hoveyda–Grubbs‐type complexes bearing cyclopropyl to cycloheptyl ether moieties in the chelating benzylidene ligand have been synthesized and investigated by spectroscopic and crystallographic methods. Their experimentally measured catalytic activity in model ring‐closing metathesis (RCM) reactions was studied at catalyst loading down to 10 ppm and compared with DFT calculations. The latter can be used as a reliable and accurate guidance in the fast and inexpensive design of new metathesis catalysts, as we were able to find a good correlation between the initiation rate and free‐energy barrier of the reaction.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorZieliński, Adam
dc.contributor.authorGajda, Roman
dc.contributor.authorVidović, Dragoslav
dc.contributor.authorSzczepaniak, Grzegorz
dc.contributor.authorTrzaskowski, Bartosz
dc.contributor.authorWoźniak, Krzysztof
dc.contributor.authorGrela, Karol
dc.contributor.authorKajetanowicz, Anna
dc.date.accessioned2024-01-25T19:34:05Z
dc.date.available2024-01-25T19:34:05Z
dc.date.issued2018
dc.description.financeNie dotyczy
dc.description.number32
dc.description.volume2018
dc.identifier.doi10.1002/EJIC.201800639
dc.identifier.issn1434-1948
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/118915
dc.identifier.weblinkhttps://doi.org/10.1002/ejic.201800639
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofEuropean Journal of Inorganic Chemistry
dc.relation.pages3675-3685
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.subject.enHomogeneous catalysis Metathesis Ruthenium Ring-Closing Metathesis Computations
dc.titleRuthenium Olefin Metathesis Catalysts Systematically Modified in Chelating Benzylidene Ether Fragment: Experiment and Computations
dc.typeJournalArticle
dspace.entity.typePublication