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(Ar-CO-C C)(PEt3)Au and (Ar-C C)(PEt3)Au complexes bearing pyrenyl and ferrocenyl groups: synthesis, structure, and luminescence properties

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cris.lastimport.scopus2024-02-12T20:35:26Z
dc.abstract.enTwo types of (acetylide)(triethylphosphine)gold(i) complexes ArCOC CAuPEt3 (1a and 1b) and ArC CAuPEt3 (2a and 2b) bearing Ar = pyren-1-yl or ferrocenyl group were synthesized and the effect of a carbonyl moiety on the structure, propensity to ligand scrambling in solution and luminescence properties were investigated. We found that the complexes bearing acetylenic ketone-derived ligands underwent ligand scrambling in solution to afford mixtures of ArCOC CAuPEt3 and [(ArCOC C)(2)Au](-)[Au(PEt3)(2)](+). The latter complexes were isolated and their structures were confirmed by single crystal X-ray diffraction studies. The aurophilic interaction of Au center dot center dot center dot Au in these complexes resulted in the formation of wire-like structures.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorKobayashi, Yasuhiro
dc.contributor.authorGłodek, Marta
dc.contributor.authorPaluch, Piotr
dc.contributor.authorPlażuk, Damian
dc.contributor.authorZakrzewski, Janusz
dc.contributor.authorKądziołka-Gaweł, Mariola
dc.contributor.authorMakal, Anna
dc.date.accessioned2024-01-24T16:55:47Z
dc.date.available2024-01-24T16:55:47Z
dc.date.copyright2018-04-12
dc.date.issued2018
dc.description.accesstimeAT_PUBLICATION
dc.description.financeNie dotyczy
dc.description.number19
dc.description.versionORIGINAL_AUTHOR
dc.description.volume47
dc.identifier.doi10.1039/C8DT01061G
dc.identifier.issn1477-9226
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/101086
dc.identifier.weblinkhttps://pubs.rsc.org/en/content/articlelanding/2018/DT/C8DT01061G
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofDalton Transactions
dc.relation.pages6702-6712
dc.rightsCC-BY
dc.sciencecloudnosend
dc.title(Ar-CO-C C)(PEt3)Au and (Ar-C C)(PEt3)Au complexes bearing pyrenyl and ferrocenyl groups: synthesis, structure, and luminescence properties
dc.typeJournalArticle
dspace.entity.typePublication