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Synthesis Method of Unsolvated Organic Derivatives of Metal Borohydrides

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dc.abstract.enA new, scalable, wet-chemistry single-pot method of synthesising pure unsolvated organic derivatives of metal borohydrides is presented. The metathetic reaction in a weakly coordinating solvent is exemplified by the synthesis of [(n-C4H9)4N][Y(BH4)4] and [Ph4P][Y(BH4)4] systems. For the latter compound, the crystal structure was solved and described. Organic borohydride salts obtained by the new method can find various applications, e.g., can be used as precursors in synthesis of hydrogen-rich mixed-metal borohydrides—promising materials for solid-state chemical storage of hydrogen.
dc.affiliationUniwersytet Warszawski
dc.contributor.authorFijałkowski, Karol
dc.contributor.authorWegner, Wojciech
dc.date.accessioned2024-01-26T09:26:40Z
dc.date.available2024-01-26T09:26:40Z
dc.date.issued2022
dc.description.financePublikacja bezkosztowa
dc.description.number23
dc.description.volume15
dc.identifier.doi10.3390/MA15238653
dc.identifier.issn1996-1944
dc.identifier.urihttps://repozytorium.uw.edu.pl//handle/item/121297
dc.identifier.weblinkhttps://www.mdpi.com/1996-1944/15/23/8653/pdf
dc.languageeng
dc.pbn.affiliationchemical sciences
dc.relation.ispartofMaterials
dc.relation.pages8653
dc.rightsClosedAccess
dc.sciencecloudnosend
dc.titleSynthesis Method of Unsolvated Organic Derivatives of Metal Borohydrides
dc.typeJournalArticle
dspace.entity.typePublication