Journal Article
No Thumbnail Available
License
CC-BY-NCCC-BY-NC - Attribution-NonCommercial

Vitamin B12 and a metal-organic framework enable the photocatalytic generation of alkyl radicals

Show metadata view
DOI
10.1039/D3CC02941G
Author
Gryko, Dorota
Chmielewski, Michał
Chołuj, Artur
Dworakowski, Krzysztof
Publication date
2023
Abstract (EN)

A versatile Co-catalyst - vitamin B12 (cobalamin) - can be photochemically reduced to its catalytically active Co(I) form under visible light irradiation, in the presence of MIL-125-NH2(Ti) as a photocatalyst and utilized for the generation of alkyl radicals. The prior reduction of cobalamin to the Co(II) form is not required in this method.

PBN discipline
chemical sciences
Journal
Chemical Communications
ISSN
1359-7345
Date release in open access
2023-08-22
Link to source
http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC02941G
Open access license
Attribution-NonCommercial